Employee profile

professor Mirosław Derewiński

Employee since 1979

Room: 238

Phone: +48 12 6395 154

E-mail: ncderewi(at)cyf-kr.edu.pl

Research topics:

Preparation of new materials with multimodal (micro/meso/macro) pore structure.



Synthesis of crystalline, microporous materials (isomorphously substituted with different metals), synthesis of silica and/or alumina based mesoporous materials.



Post-synthesis modification of micro- and mesoporous materials by thermal, hydrothermal and chemical treatments.



Synthesis of zeolite membranes and their application in separation processes.



Application of FTIR spectroscopy for in-situ measurements (acidity, kinetic of sorption…).

Methodology:

Hydrothermal synthesis in static and dynamic conditions.



FTIR spectroscopy for structural analysis, acidity/basicity determination and catalytic activity measurement.



Low-temperature N2 sorption.



27Al and 29Si MAS NMR and XRD techniques (structural analysis, structure and nature of active sites).



SEM, EDX and TEM for analysis of the texture (morphology and crystal/particle size) and elemental microanalysis.

Achievements:

DSc (2002) Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Cracow, "Preparation of zeolite based catalysts and sorbents of tailored properties".



PhD (1981) Chemistry Department, Technical University, Warsaw, "Physicochemical and catalytic properties of amorphous aluminosilicates modified with gaseous chlorine".



MSc (1974) Chemistry Department, Technical University, Warsaw, "Reactions of benzaldehyde on magnesia".







President of the Federation of European Zeolite Associations (FEZA): 2002-2004 and 2004-2006.



President of the Polish Zeolite Association :1997-1998 and 1999-2000



Fellowships



2005 - visiting professor, 1 month, France, Laboratoire "Systèmes Interfaciaux à l'Echelle Nanométrique" (SIEN) UMR 7142 CNRS, Université P. et M. Curie, Paris



2004 - visiting professor, 2 months, France, Laboratoire de Chimie Organique Physique et Cinétique Chimique Appliquées, URA 418 CNRS, Montpellier



1994 - research fellowship, 1 month, France, Laboratoire de Réactivite de Surface et Structure, URA 1106 CNRS, Université P. Et M. Curie, Paris



1991-1992 - research fellowship, 18 months, France, Laboratoire de Réactivite de Surface et Structure, URA 1106 CNRS, Université P. Et M. Curie, Paris



1988-1989 - research fellowship, 18 months, France, Laboratoire de Chimie Organique Physique et Cinétique Chimique Appliquées, URA 418 CNRS, Montpellier



1999 - research fellowship, 1 month, Spain, Instituto de Tecnologia Quimica (ITQ), UPV-CSIC, Valence. 1994-2005 - every year 2 week visits at the Institute in Valence



1996 - 2007 - research fellow, 2 weeks, Estonia, every year short visits (2 weeks) Institute of Chemical Physics and Biophysics, Estonian Academy of Sciences, Tallin,



1987 - visiting scientist, 2 months, India, National Chemical Laboratory (NCL), Pune. 1982-2003 - short (2 weeks) research visit at the NLC.



1987 - visitinf scientist,2 months, Austria, Technische Universistat, Viena. 1984-1990 - short (2 weeks) research visit at the Technische Universitat.

2019

  • Parruzot, B., Ryan, J.V., George, J. L., Motkuri, R.K., Bonnett, J. F., Seymour, L. M., Derewinski, M. A, "Multi-glass investigation of Stage III glass dissolution behaviour from 22 to 90oC triggered by the addtion of zeolite phases", Journal of Nuclear Materials, 523 (2019) 490-501
  • J. A. Lopez-Ruiz, E. Andrews, S. A. Akhade, M.-S. Lee, K. Koh, U. Sanyal, S. F. Yuk, A. J. Karkamkar, M. A. Derewinski, J. Holladay, V.-A. Glezakou, R. Rousseau, O. Y. Gutiérrez, J. D. Holladay, "Understanding the Role of Metal and Molecular Structure on the Electrocatalytic Hydrogenation of Oxygenated Organic Compounds", ACS Catalysis, 9 (2019) 9964-9972
  • K. Koh, U. Sanyal, M.-S. Lee, G. Cheng, M. Song, V.-A. Glezakou, Y. Liu, D. Li, R. Rousseau, O. Y. Gutiérrez, A. Karkamkar, M. Derewinski, J. Lercher, "Electrochemically tunable proton coupled electron transfer in Pd‐catalyzed benzaldehyde hydrogenation", Angew. Chem. Int. Ed., 10.1002/ange.201912241

2018

  • K. Onik, M. Gackowski, M.A. Derewinski, B. Sulikowski, "Mesoporous Layered Aluminosilicates Prepared from Protozeolitic Nanoclusters: Synthesis and Physicochemical and Catalytic Properties", J. Phys. Chem. C , 122 (2018) 25983-25991
  • Liu, J., Zheng, J., Barpaga, D., Sabale, S., Arey, B., Derewinski, M. A., Motkuri, R. K. , "A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications", Eur. J. Inorg. Chem., 7 (2018) 885-889
  • S. Prodinger, A. Vjunov, J. Z. Hu, J. L. Fulton, D. M. Camaioni, M. A. Derewiński, J. A. Lercher,, "Elementary Steps of Faujasite Formation Followed by in Situ Spectroscopy", Chem. Mater., 30 (2018) 888-897

2016

  • M. Gackowski, E. Bielanska, K. Szczepanowicz, P. Warszynski, M. Derewinski, "Deposition of Zeolite Nanoparticles Onto Porous Silica Monolith", Surface Innovations, 4(2) (2016) 88-101

2009

  • V. Pashkova, E. Włoch, A. Mikołajczak, M. Łaniecki, B. Sulikowski, M. Derewiński, "Composite SBA-15/MFI Type Materials: Preparation, Characterization and Catalytic Performance", Catal. Lett., 128 (2009) 64-71

2008

  • A.Burkat-Dulak, M.Derewiński "Preparation of MFI Type Zeolite with Hierachical Pores System as New Supports for Deposition of Metal Clusters", Stud. Surf. Sci. Catal., 174A (2008) 149-154
  • A. Burkat-Dulak, V. Pashkova, W. Pudło, E. Włoch, A. Jarzębski, M. Derewiński, "Nanomaterials with a Multimodal Pore Structure Based on the MFI-Type Zeolite", Polish J. Chem., 82 (2008) 1809-1822
  • M.Derewiński, K.Góra-Marek, K.Lazar, J.Datka "Nature of Active Sites in the Fe-TON Zeolites: Mössbauer and IR Studies", Stud. Surf. Sci. Catal., 174B (2008) 865-868
  • V.Pashkova, K.Góra-Marek, P.Sarv, M.Derewiński "Formation and Nature of Active Sites in the FAU- and BEA-Composites", Stud. Surf. Sci. Catal., 174B (2008) 845
  • V.Pashkova, W.Pudło, A.Jarzębski, M.Derewiński "Composite Materials Containing Zeolitic Layers Deposited on the Silica/aAumina Porous Monoliths", Stud. Surf. Sci. Catal., 174A (2008) 381-384
  • A.Burkat-Dulak, L.Lityńska, M.Derewiński "Preparation of Bifunctional Catalysts", in: "Advances Micro- and Mesoporous Materials" (K.Hadjiivanov et aol., Eds.), Heron Press, Sofia 2008, p.286-294 [ISBN 978-954-580-239-3]
  • V.Pashkova, K.Góra-Marek, L.Lityńska, M.Derewiński "Preparation of New Acid-Type Catalysts Containing Nanoclusters of Zeolites (FAU, BEA) Dispersed in the Amorphous Porous Matrix", in: "Advances Micro- and Mesoporous Materials" (K.Hadjiivanov et al., Eds.), Heron Press, Sofia 2008, p.270-277 [ISBN 978-954-580-239-3]

2007

  • V. Pashkova, P. Sarv, M. Derewiński "Composite Porous Materials Containing Zeolitic Domains Prepared by Controlled Partial Recrystallization of Amorphous Aluminosilicates", Stud. Surf. Sci. Catal., 170A (2007) 289-296

2006

  • M. Derewiński, P. Sarv, A. Mifsud "Thermal Stability and Siting of Aluminum in Isostructural ZSM-22 and Theta-1 Zeolites", Catal. Today, 114 (2006) 197-204
  • A. Zikánova, M. Derewiński, P. Sarv, P. Hudec, M. Kočiřik "The Effect of Immobilization/mobilization Processes on the Temperature Onset of a Catalyst Bed Production. Case of Ethylene Oligomerization over HZSM-5 Zeolites", Catal. Today, 114 (2006) 248-256

2005

  • K. Góra-Marek, M. Derewiński, P. Sarv, J. Datka "IR and NMR Studies of Mesoporous Alumina and Related Aluminosilicates", Catal. Today, 101 (2005) 131-138
  • P. Sarv, M. Derewiński, I. Heinmaa "Active Site Reinsertion and Redistribution in B,Al-Beta Zeolite Effected by Boron Removal", Stud. Surf. Sci. Catal., 158 (2005) 687-694
  • G. Popov, A. V. Smirnov, J. Kryściak, M. Derewiński, O. V. Borsukov, E. G. Derouane, F. Lemos, F. Fajula, I. Ivanova, "Conversion of Gas Condensate over Metal-containing MFI Catalysts", , (2005) p.351-357
  • A. Smirnov, A. Popov, O. Borsukov, M. Derewiński, F. Faula, I. Ivanova "Catalyst and Process for the Production of High-octane Fuel and LPG", Patent Federacji Rosyjskiej, RU 2243820 (2005)

2004

  • M.Derewiński, M.Machowska "Effect of Stirring on the Selective Synthesis of MEL or TON Zeolites in the Presence of 1,8-Diaminooctane", Stud. Surf. Sci. Catal., 154A (2004) 349-354

2003

  • I.Ivanova, A.Smirnov, A.Popov, M.Derewiński, F.Fajula "Catalyst and Process for the Production of High-Octane Fuel and LPG", Russian Patent Application No 2003121357

2002

  • M.Derewiński, M.Machowska, P.Sarv "Acidity and Thermal Stability of Mesoporous Aluminosilicates Synthesized by Cationic Surfactant Route", Stud. Surf. Sci. Catal,. 142 (2002), 1157-1164
  • M.Derewiński "Fizykochemia procesów otrzymywania katalizatorów i adsorbentów zeolitowych o określonych własnościach", IKiFP PAN, Kraków 2002, pp.109

1998

  • M. Derewiński, J. Kryściak, Z. Olejniczak, B. Sulikowski, G. Bueno,, "Oxidative Dehydrogenation of Propane on Large-pore Zeolites", Proc. of the NATO Advanced Study Institute, NATO ASI Series, 3/44 (1998) 397-401

1996

  • V. Cortés Corberán, R. X. Valenzuela, B. Sulikowski, M. Derewiński, Z. Olejniczak, J. Kryściak, "Gallium oxide promoted zeolite catalysts for oxidehydrogenation of propane", Catal. Today, 32 (1996) 193-204

1991

  • M. Derewiński, S. Dźwigaj, J. Haber, R. Mostowicz, B. Sulikowski, "Isomorphous Substitution in Zeolites: Catalytic and Acidic Properties", Z. Phys. Chem. (München), 171 (1991) 53-73